Crystal Structures of N2,N5,N8-Tri-p-toluenesulfonyl-2,5,8-triaza[9]-paracyclophane and N2,N5,N8-Tri-p-toluenesulfonyl-14-hydroxy-15-hydroxymethyl-O14,O15'-isopropylidene-11-methyl-2,5,8-triaza[9](2,5)pyridinophane.
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چکیده
منابع مشابه
Direct Oxidation of Aldehydes to Methyl Esters with Urea Hydrogen Peroxide and p-Toluenesulfonyl Chloride
Combination of urea hydrogen peroxide and p-toluenesulfonyl chloride in methanol was proved to be facile and highly efficient for the oxidative methyl esterification of various aldehydes to the corresponding carboxylic methyl esters.
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In the title compound C(21)H(21)P, the P atom is situated on a crystallographic threefold rotatory-inversion axis, resulting in threefold rotation symmetry of the title compound. The dihedral angles between the symmetry-related benzene rings are 87.40 (18)°.
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In the title compound, C(26)H(23)N, the complete molecule is generated by crystallographic mirror symmetry, with the N atom and four C atoms lying on the reflection plane. The dihedral angles between the pyridine ring and pendant benzene rings are 2.9 (1), 14.1 (1) and 14.1 (1)°. Neighbouring mol-ecules are stabilized through inter-molecular π-π inter-actions along the c axis [centroid-to-centr...
متن کاملA smooth rearrangement of N-p-toluenesulfonyl 2-tert-butyldiphenylsilylmethyl-substituted azetidines into N-p-toluenesulfonyl 3-tert-butyldiphenylsilyl-substituted pyrrolidines.
The rearrangement of N-p-toluenesulfonyl 2-tert-butyldiphenylsilylmethyl-substituted azetidines into 3-tert-butyldiphenylsilyl-substituted pyrrolidines under Lewis acid conditions in dichloromethane involves 1,2-migration of silicon through a siliranium ion. The formation of siliranium ion was discovered not to be in concert with σ(C-N) cleavage from stereochemical analysis of the pyrrolidine p...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 1998
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.14.1025